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    ChemicalBook >> CAS DataBase List >>Acetamiprid

    Acetamiprid

    CAS No.
    135410-20-7
    Chemical Name:
    Acetamiprid
    Synonyms
    (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine;Prize;Pristine;Piorun;NFK 17;MORTAL;TD 2480;TD 2472;Stonkat;MOSPILAN
    CBNumber:
    CB9351350
    Molecular Formula:
    C10H11ClN4
    Molecular Weight:
    222.67
    MDL Number:
    MFCD06201842
    MOL File:
    135410-20-7.mol
    Last updated:2023-09-20 16:43:00

    Acetamiprid Properties

    Melting point 101-103°C
    Boiling point 352.4±52.0 °C(Predicted)
    Density 1.17
    vapor pressure <1 x 10-6 Pa (25 °C)
    storage temp. Inert atmosphere,2-8°C
    solubility DMSO: Soluble; Methanol: Soluble
    form A solid
    pka -0.44±0.10(Predicted)
    Water Solubility 4200 mg l-1 (25 °C)
    InChI InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
    InChIKey WCXDHFDTOYPNIE-RIYZIHGNSA-N
    SMILES C(/N(CC1=CC=C(Cl)N=C1)C)(=N\C#N)\C
    CAS DataBase Reference 135410-20-7(CAS DataBase Reference)
    FDA UNII 5HL5N372P0
    NIST Chemistry Reference Acetamipride(135410-20-7)
    EPA Substance Registry System Acetamiprid (135410-20-7)

    SAFETY

    Risk and Safety Statements

    Symbol(GHS)  GHS hazard pictograms
    GHS06
    Signal word  Danger
    Hazard statements  H301-H330-H412
    Precautionary statements  P260-P273-P284-P301+P310-P310
    Hazard Codes  T
    Risk Statements  23/25-57-52/53
    Safety Statements  45-61
    RIDADR  2588
    RTECS  KJ4235200
    HazardClass  6.1(b)
    PackingGroup  III
    HS Code  29333990
    NFPA 704
    0
    2 0

    Acetamiprid price More Price(16)

    Manufacturer Product number Product description CAS number Packaging Price Updated Buy
    Cayman Chemical 24129 Acetamiprid ≥98% 135410-20-7 10mg $27 2023-06-20 Buy
    Cayman Chemical 24129 Acetamiprid ≥98% 135410-20-7 50mg $64 2023-06-20 Buy
    Cayman Chemical 24129 Acetamiprid ≥98% 135410-20-7 100mg $90 2023-06-20 Buy
    TRC A150800 Acetamiprid 135410-20-7 5g $1210 2021-12-16 Buy
    Biosynth Carbosynth FA16947 Acetamiprid 135410-20-7 250mg $50 2021-12-16 Buy
    Product number Packaging Price Buy
    24129 10mg $27 Buy
    24129 50mg $64 Buy
    24129 100mg $90 Buy
    A150800 5g $1210 Buy
    FA16947 250mg $50 Buy

    Acetamiprid Chemical Properties,Uses,Production

    The new pesticide

    Acetamiprid, also known as mospilan, is a new kind of pesticides. It is nitro methylene heterocyclic compounds. It can act on nicotinic acetylcholine receptor of the insect nervous system synapses, interfere the insect nervous system stimulation conduction, cause neurological pathways obstruction, and result in the accumulation of the neurotransmitter acetylcholine in the synapse. Then it can result in the paralysis of insect and eventually death. Acetamiprid has tag and stomach toxicity effect. Meanwhile it has a strong penetration, readily availability, and long duration.
    Acetamiprid can be used for the prevention and control of aphids, planthoppers, thrips, lepidopteron and other pests on the rice, vegetables, fruit, tea bushes. At the concentration of 50 to 100 mg/L, acetamiprid can effectively control aphid, vegetables aphid, peach borer and it can kill eggs.

    Physicochemical property

    The original drug acetamiprid is white crystalline. Its content is more than 99%, melting point is 101~103.3℃, and vapor pressure is less than 0.33×10-6Pa (25℃). Acetamiprid is slightly soluble in water, and its solubility in the water is 4.2g/L. Acetamiprid is also soluble in acetone, methanol, ethanol, dichloromethane, chloroform, acetonitrile and the like. It is stable in the neutral or slightly acidic medium, and it can be stored at room temperature for 2 years. It can gradually hydrolyze when pH is 9 at 45℃. It is stable in sunlight.
    The above information is edited by the Chemicalbook Ge Qian.

    Toxicity

    According to our pesticide toxicity grading standards, acetamiprid is moderately toxic pesticides. Acute oral LD50 of rat is 146~217mg/kg weight. It has no irritation on the skin and eye. It has no mutagenic effect according to the animal tests. Acetamiprid has low toxicity to human and animal, small lethality to predators, low toxicity to fish and little effect on bees. Acetamiprid can be used to control homopteran pests of fruit trees and vegetables. It can be used to control soil insect when using granules as soil.

    Usage

    1. Control of cucumber aphid. Pesticides should be sprayed during the full incidence beginning period of cucumber aphids. 40~50ml of 3% Acetamiprid, added 50~60kg water can be uniform sprayed. It will have a good effect on melon aphid. The efficacy can remain more than fifty days even in wet years,.
    2. Control of apple aphids. 3% Mospilan with 2000~2500 times spray can be used during the apple tree growing period and the full incidence beginning period of aphids. It has a good effect on aphids and has good resistance to rain erosion. The efficacy can remain more than twenty days.
    3. Control citrus aphids. 3% Mospilan with 2000~2500 times spray can be used during the full incidence beginning period of aphids. It has a good and persistent effect on citrus. It is safe for citrus. It has no phytotoxicity under normal use.

    Considerations

    1. If there are mulberry fields nearby, acetamiprid should not be sprayed on mulberry leaves because this agent is toxic for the silkworm.
    2. Acetamiprid can’t be mixed with strong base agents (bordeaux mixture, lime sulfur, etc.).
    3. The toxicity of acetamiprid to human and animal is low. But if it is drinked, one should be taken to the hospital to be given gastric lavage immediately and keep quiet.

    Uses

    1. Acetamiprid belongs to the same series with imidacloprid. But its nsecticidal spectruma is broader than imidacloprid. It mainly has a better effect on cucumbers aphids, apples aphids, citrus aphids and tobacco aphids. Since the mechanism of acetamiprid is unique, it have a good effect on pests that can cause resistance to organophosphorus, carbamates and pyrethroids pesticides.
    2. Efficient, broad-spectrum chlorinated insecticides.

    Chemical Properties

    Pale Yellow Solid

    Uses

    A novel neonicotinid insecticide against Holotrichia consanguinea in sugarcane. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumb lebee colonies grow poorly and produce fewer queens.

    Uses

    Acetamiprid is a systemic insecticide for soil and foliar application. It is used to control Hemiptera, especially aphids, Thysanoptera and Lepidoptera on a wide range of crops, especially vegetables, fruit and tea.

    Definition

    ChEBI: The (E)-stereoisomer of acetamiprid.

    Agricultural Uses

    Insecticide: This class of pesticides are chemically related to nicotine and used on corn and soybean seeds and are used to control sucking and chewing insects, and soil insects including aphids, beetles, fruit moth, leaf-hoppers and-miners, thrips, whiteflies [83] . Also used to control fleas on domestic animals.

    Metabolic pathway

    Acetamiprid is relatively stable to hydrolysis and to photodegradation by sunlight. It is rapidly degraded in soils to form 6-chloropyridinyldimethylamine and 6-chloronicotinic acid. The main pathways of metabolism in plants are N-demethylation and subsequent oxidation affording 6-chloronicotinic acid and 6-chloropicolyl alcohol. Two N-cyanoamidines were formed after application of acetamiprid to cabbage leaves. No information is available on the fate of the insecticide in insects or mammals.

    Degradation

    Acetamiprid is stable in buffer solutions at pH 4, 5 and 7 and under sunlight. It is degraded slowly at pH 9 (45 °C) (PM). In a study of its hydrolysis acetamiprid was converted quantitatively to N-methyl- (6-chloro-3-pyridyl)methylamine (2) in 0.5-1 N sodium hydroxide at 90-95°C in 2 hours (see Scheme 1). N-Demethyl-acetamiprid (3) was converted to (6-chloro-3-pyridyl)methylamine(4) at the same rate and under similar conditions (Tokieda et al., 1997).

    1558-82-3
    120739-62-0
    135410-20-7
    Synthesis of Acetamiprid from Ethyl N-cyanoethanimideate and N-[(6-CHLOROPYRIDIN-3-YL)METHYL]-N-METHYLAMINE

    Acetamiprid Preparation Products And Raw materials

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    View Lastest Price from Acetamiprid manufacturers

    Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
    Acetamiprid pictures 2023-11-29 Acetamiprid
    135410-20-7
    US $15672.00 / Tons 1Tons 99.99% 100Tons Hebei Dangtong Import and export Co LTD
    Acetamiprid pictures 2023-09-19 Acetamiprid
    135410-20-7
    US $0.00 / kg 1kg 99% 20tons Hebei Yanxi Chemical Co., Ltd.
    Acetamiprid pictures 2023-07-29 Acetamiprid
    135410-20-7
    US $10.00 / kg 1kg 99.99% 50000tons Henan Bao Enluo International TradeCo.,LTD
    • Acetamiprid pictures
    • Acetamiprid
      135410-20-7
    • US $15672.00 / Tons
    • 99.99%
    • Hebei Dangtong Import and export Co LTD
    • Acetamiprid pictures
    • Acetamiprid
      135410-20-7
    • US $0.00 / kg
    • 99%
    • Hebei Yanxi Chemical Co., Ltd.
    • Acetamiprid pictures
    • Acetamiprid
      135410-20-7
    • US $10.00 / kg
    • 99.99%
    • Henan Bao Enluo International TradeCo.,LTD

    Acetamiprid Spectrum

    Ethanimidamide, N-(6-chloro-3-pyridinyl)methyl-N-cyano-N-methyl-, (1E)- acetamiprid (iso) (1E)-N-[(6-Chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide Acetamiprid ADA 06200 NFK 17 Piorun Stonkat TD 2472 TD 2472-01 TD 2480 (E)-N-(6-CHLORO-3-PYRIDYLMETHYL)-N'-CYANO-N-METHYLACETAMIDINE MORTAL MOSPILAN MOSPILDATE N-((6-CHLOROPYRIDIN-3-YL)METHYL)-N'-CYANO-N-METHYLACETAMIDINE ACETAMIPRID 98%TC Acetamiprid 100mg [135410-20-7] (E)-N-((6-chloropyridin-3-yl)methyl)-N'-cyano-N- methylacetimidamide (E)-acetamiprid (160430-64-8) acetamiprid Acetamiprid20%SC Acetamiprid@100 μg/mL in AcCN AcetamipridSolution,1,000mg/L,1ml AcetamipridSolution,400mg/L,1ml Acetamiprid@1000 μg/mL in Acetonitrile Powder systemic Organic Insecticide for fruit trees , cas 135410-20-7 (E)-acetamipri GIOVANNI PAPAGNI (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine Pristine Prize 99% acetamiprid technical 135410-20-7 3540-20-7 35410-20-7 Agrochemical Agro-Products Aromatics Heterocycles 135410-20-7
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