ChemicalBook >> CAS DataBase List >>4-Methylbenzophenone

4-Methylbenzophenone

4-Methylbenzophenone structure

CAS No.: 134-84-9

Chemical Name:: 4-Methylbenzophenone

Synonyms: phenyl(p-tolyl)methanone;Methanone, (4-methylphenyl)phenyl-;4-methybenzophenone;APi-MBP;NSC 4898;usafdo-54;YF-PI MBP;USAF DO-54;IHT-PI MBP;HRcure-MBZ

CBNumber:: CB4261278

Molecular Formula:: C14H12O

Molecular Weight:: 196.24

MDL Number:: MFCD00008553

MOL File:: 134-84-9.mol

MSDS File:: SDS

Last updated:2023-11-14 13:15:32

Request For Quotation

4-Methylbenzophenone Properties

Melting point	56.5-57 °C (lit.)
Boiling point	326 °C (lit.)
Density	0.9926
vapor pressure	0.059Pa at 25℃
refractive index	1.5920 (estimate)
Flash point	143 °C
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Crystalline Powder or Crystals
color	White to beige
Odor	faint odor
Water Solubility	Insoluble in water.
Merck	14,7317
BRN	1909310
InChIKey	WXPWZZHELZEVPO-UHFFFAOYSA-N
LogP	3.69 at 25℃
CAS DataBase Reference	134-84-9(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	B2F68X17BM
NIST Chemistry Reference	Methanone, (4-methylphenyl)phenyl-(134-84-9)
EPA Substance Registry System	4-Methylbenzophenone (134-84-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P280-P301+P312-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

22-36/38-36/37/38

Safety Statements

24/25-36-26

WGK Germany

RTECS

DJ1750000

Hazard Note

Harmful/Irritant

TSCA

Yes

HS Code

29143990

NFPA 704

	0
0		0

4-Methylbenzophenone price More Price(30)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	M29959	4-Methylbenzophenone 99%	134-84-9	10g	$43.3	2023-06-20	Buy
Sigma-Aldrich	00373	4-Methylbenzophenone analytical standard	134-84-9	100mg	$95.9	2022-05-15	Buy
TCI Chemical	M1248	4-Methylbenzophenone >95.0%(GC)	134-84-9	25g	$27	2023-06-20	Buy
TCI Chemical	M1248	4-Methylbenzophenone >95.0%(GC)	134-84-9	250g	$162	2023-06-20	Buy
Alfa Aesar	A15479	4-Methylbenzophenone, 98%	134-84-9	50g	$68.3	2023-06-20	Buy

Product number	Packaging	Price	Buy
M29959	10g	$43.3	Buy
00373	100mg	$95.9	Buy
M1248	25g	$27	Buy
M1248	250g	$162	Buy
A15479	50g	$68.3	Buy

4-Methylbenzophenone Chemical Properties,Uses,Production

Chemical Properties

white to beige crystalline powder or crystals

Uses

4-Methylbenzophenone may be used as a reference standard for the determination of the analyte in breakfast cereals, paperboard food packaging and packed milk by various chromatography techniques.

Uses

4-Methylbenzophenone is used as clear coatings for wood, plastic and metal, overprint varnish.

Uses

Benzophenone estrogenicity toxicity structure activity.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 1223, 1960 DOI: 10.1021/ja01490a047
Tetrahedron Letters, 40, p. 3109, 1999 DOI: 10.1016/S0040-4039(99)00476-1
Synthesis, p. 776, 1977 DOI: 10.1055/s-1977-24573

General Description

4-Methylbenzophenone is a photo-initiator for printing inks, mainly applied to the cardboard boxes used for packing. It is reported to be a non-genotoxic carcinogen. However, it can contaminate foodstuffs when it comes in contact with the package contents.

Flammability and Explosibility

Not classified

Safety Profile

Poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Purification Methods

Crystallise the ketone from MeOH, Et2O (m 58-59o) or pet ether. The cis-oxime has m 154o(153-156o) (from EtOH), and the trans-oxime has m 114-116o (from pet ether). [Beilstein 7 H 440, 7 III 2127, 7 IV 1403.]

Structure and conformation

4-Methylbenzophenone was one of the first organic compounds for which polymorphism was observed. It crystallizes in two modifications, the stable monoclinic α-form (mp 59°C) and a metastable trigonal β-form (mp 55 ℃). The metastable β-form is rather stable and almost indefinitely preserved if not subjected to severe mechanical load or brought into contact with the stable form. If it converts into a stable form, the crystal becomes milky white and non-transparent due to micro-cracking. There are no conditions under which the β-form is more stable than the α-form. 4-Methylbenzophenone crystallizes in a monoclinic stable form (mp 59 ℃) with a = 5.70 Å, b = 13.89 Å, c = 14.08 Å, p = 95.18° and space group P2_1/c, and a trigonal metastable form (mp 55°C) with a = 9.12 Å, c = 11.28 Å and space groups P3₁, or P3₂[1].

References

[1] H. Kutzke, H. Klapper, M. Al-Mansour. "Stable and metastable crystal phases of 4-methylbenzophenone." Journal of Molecular Structure 374 1 (1995): 129–135.

4-Methylbenzophenone synthesis

Synthesis of 4-Methylbenzophenone from 4-Tolylboronic acid and Benzaldehyde

4-Methylbenzophenone Preparation Products And Raw materials

Raw materials

4-Methylbenzhydrol p-Tolualdehyde Bromobenzene

Preparation Products

4-methylbenzhydrylamine

4-Methylbenzophenone Suppliers

Global( 537)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Tianjin Huiren Chemtech Co., Ltd	+8613672008665	huirentech@foxmail.com	China	110	58
Hebei Mojin Biotechnology Co., Ltd	15028179902 +8615028179902	sales@hbmojin.com	China	12242	58
Henan Bao Enluo International TradeCo.，LTD	+86-17331933971 +86-17331933971	deasea125996@gmail.com	China	2506	58
Hebei Fengqiang Trading Co., LTD	+8613373049370	kaia@hbfengqiang.com	China	982	58
Anhui Ruihan Technology Co., Ltd	+8617756083858	daisy@anhuiruihan.com	China	994	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29767	60
Henan DaKen Chemical CO.,LTD.	+86-0371-66670886	info@dakenchem.com	China	14736	58
Dalian Richfortune Chemicals Co., Ltd	0411-84820922 8613904096939	sales@richfortunechem.com	China	304	57
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21722	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	fandachem@gmail.com	China	9365	55

Supplier	Advantage
Tianjin Huiren Chemtech Co., Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Henan Bao Enluo International TradeCo.，LTD	58
Hebei Fengqiang Trading Co., LTD	58
Anhui Ruihan Technology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Henan DaKen Chemical CO.,LTD.	58
Dalian Richfortune Chemicals Co., Ltd	57
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55

View Lastest Price from 4-Methylbenzophenone manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-11-29	4-Methylbenzophenone 134-84-9	US $0.00 / KG	1KG	99%	500mt	Jinan Finer Chemical Co., Ltd
2023-10-12	4-Methylbenzophenone 134-84-9	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-26	4-Methylbenzophenone 134-84-9	US $0.00-0.00 / kg	1kg	0.99	100tons	Hebei Yanxi Chemical Co., Ltd.

4-Methylbenzophenone
134-84-9
US $0.00 / KG
99%
Jinan Finer Chemical Co., Ltd

4-Methylbenzophenone
134-84-9
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

4-Methylbenzophenone
134-84-9
US $0.00-0.00 / kg
0.99
Hebei Yanxi Chemical Co., Ltd.

4-Methylbenzophenone Spectrum

4-Methylbenzophenone(134-84-9)MS 4-Methylbenzophenone(134-84-9)¹HNMR 4-Methylbenzophenone(134-84-9)¹³CNMR 4-Methylbenzophenone(134-84-9)IR1 4-Methylbenzophenone(134-84-9)IR2 4-Methylbenzophenone(134-84-9)Raman

134-84-9(4-Methylbenzophenone)Related Search:

2-ACETOXY-3'-METHYLBENZOPHENONE 2-ACETOXY-2',5'-METHYLBENZOPHENONE 1-AMINO-2-METHYLANTHRAQUINONE 2-METHOXY-3'-METHYLBENZOPHENONE TOLUALDEHYDES

3-METHOXYL-4-HYDROXYL-5-NITROBENZENYL,4'-METHYLBENZENYL KETONE Methylbenzophenone PHENYL RESIN 2-CHLORO-2-HYDROXY-5-METHYLBENZOPHENONE (-)-2-[METHYLAMINO]-1-PHENYLPROPANE

5-CHLORO-2-HYDROXY-4-METHYLBENZOPHENONE 2-BROMO-3'-CHLORO-4'-METHYLBENZOPHENONE 1-AMINO-4-BROMO-2-METHYLANTHRAQUINONE 2-(HYDROXYMETHYL)ANTHRAQUINONE PHENYL VALERATE

2-IODO-4'-METHYLBENZOPHENONE 2-ACETOXY-2',3'-METHYLBENZOPHENONE 2,4'-DICHLORO-3'-METHYLBENZOPHENONE

1of4

P-TOLYL PHENYL KETONE P-METHYLBENZOPHENONE PHENYL P-TOLYL KETONE PHENYL 4-TOLYL KETONE P-BENZOYL TOLUENE (4-methylphenyl)phenyl-methanon 4-METHYLBENZOPHENONE (4-METHYLPHENYL)PHENYLMETHANONE 4-methyl-benzophenon 4-Benzoyltoluene 4-Methylphenyl(phenyl) ketone 4-Methylphenyl(phenyl)ketone 4-Methylbenzophenone,97% (Phenyl)(4-Methylphenyl)Methanone NSC 4898 Phenyl(4-tolyl)Methanone 4-Methylphenyl-Benzophenone 4-Methylbenzopheone 4-Methylbenzophenone, 97% 50GR 4-Methyl twophenyl Methyl ketone (4-Methylphenyl)phenylmethanone phenyl p-tolyl ketone Benzophenone, 4-methyl- methyl-p-benzophenon p-Benzophenone, methyl- USAF DO-54 usafdo-54 4-Methylbenzophenone95% p-Phenyl tolyl ketone 4-METHYLBENZOPHENONE 99+% 4-methlybenzophenone IHT-PI MBP Photoinitiator-MBP YF-PI MBP 4-Methylbenzophenone Solution, 100ppm HRcure-MBZ OMNIRAD 4MBZ 4-Methylbenzophenone Photoinitiator MBP 4-Methylbenzophenone> 4-Methylbenzophenone Mbp phenyl(p-tolyl)methanone 4-methybenzophenone Methanone, (4-methylphenyl)phenyl- Lencolo 5035 Sinocure? MBP / 4-methylbenzophenone Rilpivirine Impurity 21 APi-MBP 134-84-9 KETONE Aromatics Mutagenesis Research Chemicals Benzophenone Organic Photoinitiators Polymerization Initiators Aromatic Benzophenones & Derivatives (substituted) 134-84-9